A. Faucitano , A. Buttafava , F. Martinotti , V. Comincioli , F. Gratani
{"title":"Kinetic modelling of the post-irradiation oxidation of isotactic polypropylene","authors":"A. Faucitano , A. Buttafava , F. Martinotti , V. Comincioli , F. Gratani","doi":"10.1016/0144-2880(86)90017-5","DOIUrl":null,"url":null,"abstract":"<div><p>A kinetic model for the post-irradiation oxidation of isotactic polypropylene films has been obtained giving concentration profiles of some reactants and products as a function of time and of the spatial co-ordinates. The diffusion parameters for oxygen and the rate constants for the main steps in the hydroperoxidative cycle were determined for the reaction within film depth of 12–40 μm.</p></div>","PeriodicalId":101036,"journal":{"name":"Polymer Photochemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1986-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0144-2880(86)90017-5","citationCount":"3","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Photochemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0144288086900175","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3
Abstract
A kinetic model for the post-irradiation oxidation of isotactic polypropylene films has been obtained giving concentration profiles of some reactants and products as a function of time and of the spatial co-ordinates. The diffusion parameters for oxygen and the rate constants for the main steps in the hydroperoxidative cycle were determined for the reaction within film depth of 12–40 μm.