Synthesis and Optical Properties of Silica-Silver Nanocomposite

IF 0.4 Q4 NANOSCIENCE & NANOTECHNOLOGY Nano Hybrids and Composites Pub Date : 2022-04-05 DOI:10.4028/p-vdn61s
I. David, E. O. Dare, Olayinka J. Olaniyan
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Abstract

Silica (SiO2) is a basic raw material that is widely used in optical, ceramics and other industries. Therefore, there is important need to study and improve its optical properties. In this study, silica was extracted and precipitated from maize cob and sodium silicate respectively using simple chemical methods. Silica-silver nanocomposite was produced by hybridization of silica with silver nanoparticles synthesized from plant extract. The source of silica that has been chosen for hybridization is sodium silicate which is effective compared to maize cob. The samples were characterized by UV-Visible, TEM and XRD analyses. UV-Visible results confirmed the presence of silica at 290nm and silver at 425nm. TEM image shows the dispersion of silver within the silica matrixes which gives silica capped silver morphology which is also evidence of hybridization. XRD also confirmed the presence and mixture of silica and silver at 2Ɵ° values between 18.5°-34.5° and 39.5°-65° respectively. The increase in absorbance value of silica before and after hybridization (0.5 to 1.0 respectively) confirms the improvement in optical properties of silica which is an effect of silver in enhancing the optical properties of silica. Therefore, silica-silver nanocomposite can be used for various optical materials.
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硅-银纳米复合材料的合成及其光学性能
二氧化硅(SiO2)是一种基础原料,广泛应用于光学、陶瓷等行业。因此,有必要研究和改善其光学性能。本研究采用简单的化学方法分别从玉米芯和水玻璃中提取和沉淀二氧化硅。将二氧化硅与从植物提取物中合成的纳米银进行杂交制备二氧化硅-银纳米复合材料。选用硅酸钠作为杂交材料,与玉米芯相比,硅酸钠的杂交效果较好。采用紫外可见光谱(UV-Visible)、透射电镜(TEM)和x射线衍射(XRD)对样品进行了表征。紫外可见结果证实了二氧化硅在290nm和银在425nm的存在。透射电镜图像显示银在硅基体内分散,形成硅包覆银的形态,这也是杂化的证据。XRD也证实了硅和银在2Ɵ°值分别为18.5°-34.5°和39.5°-65°范围内的存在和混合。杂化前后二氧化硅吸光度值的增加(分别为0.5 ~ 1.0)证实了二氧化硅光学性能的改善,这是银对二氧化硅光学性能的增强作用。因此,硅银纳米复合材料可用于各种光学材料。
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Nano Hybrids and Composites
Nano Hybrids and Composites NANOSCIENCE & NANOTECHNOLOGY-
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