Reaction of Sn(II) Adduct with MCl2 [M = Mn(II), Fe(II), Co(II), Ni(II), and Cu(II)]

K. Siddiqi, Hina Afaq, A. Umar, Shahab A. A. Nami, R. Singh
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Abstract

Abstract Complexes of SnCl2 · py with MCl2, where M = Mn(II), Fe(II), Co(II), Ni(II), and Cu(II), have been prepared and characterized by the elemental analysis, TGA, DTA, EPR, and IR spectra. All the compounds prepared are stable at room temperature but they are hygroscopic in nature. Substitution reactions of SnCl2 · py(MCl2) by dithiocarbamate afforded (SnCl2 · py)2M(dtc)2. An octahedral geometry for the metal dithiocarbamates has been proposed.
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制备了SnCl2·py与MCl2配合物,其中M = Mn(II), Fe(II), Co(II), Ni(II)和Cu(II),并通过元素分析,TGA, DTA, EPR和IR光谱对其进行了表征。所有制备的化合物在室温下都是稳定的,但它们在本质上是吸湿的。二硫代氨基甲酸酯对SnCl2·py(MCl2)的取代反应得到(SnCl2·py)2M(dtc)2。提出了金属二硫代氨基甲酸酯的八面体结构。
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