M. A. Barique, Y. Matsuda, Kazuma Matsuyama, S. Tasaka
{"title":"Ferroelectric behavior in vinylidene chloride copolymers","authors":"M. A. Barique, Y. Matsuda, Kazuma Matsuyama, S. Tasaka","doi":"10.1080/07315171.2019.1647704","DOIUrl":null,"url":null,"abstract":"Abstract Ferroelectric behavior was observed in the crystalline copolymers of vinylidene chloride (VDC) with vinylchloride (VC) and with methylacrylate (MA). A D-E hysteresis loop for P(VDC/VC) copolymer observed at above its glass transition temperature indicates the ferroelectricity of this copolymer. The remanent polarization was between 30 and 122 mC/m2, and pyroelectric constants of the copolymers was stable up to almost their melting points. The results of FTIR and XRD suggested that the electric behaviors of P(VDC/VC) copolymers were caused by the orientation of C-Cl dipoles in VDC chains in the crystal region to form a polar structure in a high electric field.","PeriodicalId":50451,"journal":{"name":"Ferroelectrics Letters Section","volume":"2 1","pages":"1 - 7"},"PeriodicalIF":1.3000,"publicationDate":"2019-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ferroelectrics Letters Section","FirstCategoryId":"101","ListUrlMain":"https://doi.org/10.1080/07315171.2019.1647704","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, CONDENSED MATTER","Score":null,"Total":0}
引用次数: 1
Abstract
Abstract Ferroelectric behavior was observed in the crystalline copolymers of vinylidene chloride (VDC) with vinylchloride (VC) and with methylacrylate (MA). A D-E hysteresis loop for P(VDC/VC) copolymer observed at above its glass transition temperature indicates the ferroelectricity of this copolymer. The remanent polarization was between 30 and 122 mC/m2, and pyroelectric constants of the copolymers was stable up to almost their melting points. The results of FTIR and XRD suggested that the electric behaviors of P(VDC/VC) copolymers were caused by the orientation of C-Cl dipoles in VDC chains in the crystal region to form a polar structure in a high electric field.
期刊介绍：
Ferroelectrics Letters is a separately published section of the international journal Ferroelectrics. Both sections publish theoretical, experimental and applied papers on ferroelectrics and related materials, including ferroelastics, ferroelectric ferromagnetics, electrooptics, piezoelectrics, pyroelectrics, nonlinear dielectrics, polymers and liquid crystals.
Ferroelectrics Letters permits the rapid publication of important, quality, short original papers on the theory, synthesis, properties and applications of ferroelectrics and related materials.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
