Catalytic Degradation of Safranin T in Aqueous Medium Using Non-conventional Processes

V. Sydorchuk, S. Khalameida, B. Charmas, J. Skubiszewska-Zięba, V. Zazhigalov, L. Davydenko
{"title":"Catalytic Degradation of Safranin T in Aqueous Medium Using Non-conventional Processes","authors":"V. Sydorchuk, S. Khalameida, B. Charmas, J. Skubiszewska-Zięba, V. Zazhigalov, L. Davydenko","doi":"10.1515/jaots-2016-0176","DOIUrl":null,"url":null,"abstract":"Abstract Eleven TiO2 powders as catalysts have been studied in process of safranin T degradation in aqueous medium using mechanochemical, microwave and ultrasonic techniques. The degree of degradation has been controlled by means of spectrophotometric analysis of safranin T solutions before and after treatment and total organic carbon measurements. XRD, DTA-TG and BET analysis, FTIR spectroscopy and mass spectrometry of initial and spent catalysts have been carried out for explanation of obtained results. It has been established that the catalytic activity of TiO2 under mechanochemical treatment depends on phase composition and dispersity (specific surface area). Particularly, catalytic activity of mono-phase titanias inversely depends on specific surface area of initial catalyst. Sono- and microwave catalytic degradation were less effective.","PeriodicalId":14870,"journal":{"name":"Journal of Advanced Oxidation Technologies","volume":"48 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2017-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Advanced Oxidation Technologies","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1515/jaots-2016-0176","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q","JCRName":"Chemistry","Score":null,"Total":0}
引用次数: 5

Abstract

Abstract Eleven TiO2 powders as catalysts have been studied in process of safranin T degradation in aqueous medium using mechanochemical, microwave and ultrasonic techniques. The degree of degradation has been controlled by means of spectrophotometric analysis of safranin T solutions before and after treatment and total organic carbon measurements. XRD, DTA-TG and BET analysis, FTIR spectroscopy and mass spectrometry of initial and spent catalysts have been carried out for explanation of obtained results. It has been established that the catalytic activity of TiO2 under mechanochemical treatment depends on phase composition and dispersity (specific surface area). Particularly, catalytic activity of mono-phase titanias inversely depends on specific surface area of initial catalyst. Sono- and microwave catalytic degradation were less effective.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
非常规工艺在水介质中的催化降解红花素T
摘要采用机械化学、微波和超声波等技术,研究了11种TiO2粉末作为催化剂在水介质中降解红花素T的过程。采用分光光度法对处理前后的藏红花素T溶液进行了分析,并测定了总有机碳。对初始催化剂和废催化剂进行了XRD、DTA-TG和BET分析、FTIR光谱和质谱分析,对所得结果进行了解释。已经确定,机械化学处理下TiO2的催化活性取决于相组成和分散性(比表面积)。特别是,单相钛的催化活性与初始催化剂的比表面积成反比。声纳和微波催化降解效果较差。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
CiteScore
0.88
自引率
0.00%
发文量
0
审稿时长
1 months
期刊介绍: The Journal of advanced oxidation technologies (AOTs) has been providing an international forum that accepts papers describing basic research and practical applications of these technologies. The Journal has been publishing articles in the form of critical reviews and research papers focused on the science and engineering of AOTs for water, air and soil treatment. Due to the enormous progress in the applications of various chemical and bio-oxidation and reduction processes, the scope of the Journal is now expanded to include submission in these areas so that high quality submission from industry would also be considered for publication. Specifically, the Journal is soliciting submission in the following areas (alphabetical order): -Advanced Oxidation Nanotechnologies -Bio-Oxidation and Reduction Processes -Catalytic Oxidation -Chemical Oxidation and Reduction Processes -Electrochemical Oxidation -Electrohydraulic Discharge, Cavitation & Sonolysis -Electron Beam & Gamma Irradiation -New Photocatalytic Materials and processes -Non-Thermal Plasma -Ozone-based AOTs -Photochemical Degradation Processes -Sub- and Supercritical Water Oxidation -TiO2 Photocatalytic Redox Processes -UV- and Solar Light-based AOTs -Water-Energy (and Food) Nexus of AOTs
期刊最新文献
Catalytic Ozonation of Ciprofloxacin over Cerium Oxide Modified SBA-15 and Toxicity Assessment towards E. coli Degradation of C.I. Acid Red 51 and C.I. Acid Blue 74 in Aqueous Solution by Combination of Hydrogen Peroxide, Nanocrystallite Zinc Oxide and Ultrasound Irradiation Degradation of Cyanide using Stabilized S, N-TiO2 Nanoparticles by Visible and Sun Light Environmental Matrix Effects on Degradation Kinetics of Ibuprofen in a UV/ Persulfate System An Overview of Ozone Research
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1