{"title":"The Use of 27Al NMR to Study Aluminum Compounds: A Survey of the Last 25 Years","authors":"C. Martineau, F. Taulelle, M. Haouas","doi":"10.1002/9780470682531.PAT0840","DOIUrl":null,"url":null,"abstract":"Use of 27Al nuclear magnetic resonance (NMR) spectroscopy for the study of the chemistry of aluminum in a variety of compounds during the last 25 years is reported. A compilation of NMR data, including chemical shifts and heteronuclear scalar couplings, is provided for a wide range of families of aluminum compounds in both solution and solid state. Recent methodological and technological advances in the field of quadrupolar NMR are detailed and their applications to 27Al nucleus are illustrated. The potential of this technique is exemplified with some representative studies of relevance to mineral, biological, and organic aluminum-based systems. \n \n \nKeywords: \n \n27Al nucleus; \naluminum chemistry; \nchemical shifts; \nmaterials; \nnuclear magnetic resonance; \norganoaluminum; \nquadrupolar relaxation; \nscalar coupling; \nspectroscopy","PeriodicalId":20036,"journal":{"name":"Patai's Chemistry of Functional Groups","volume":"20 1","pages":"1-51"},"PeriodicalIF":0.0000,"publicationDate":"2016-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"8","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Patai's Chemistry of Functional Groups","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/9780470682531.PAT0840","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 8
Abstract
Use of 27Al nuclear magnetic resonance (NMR) spectroscopy for the study of the chemistry of aluminum in a variety of compounds during the last 25 years is reported. A compilation of NMR data, including chemical shifts and heteronuclear scalar couplings, is provided for a wide range of families of aluminum compounds in both solution and solid state. Recent methodological and technological advances in the field of quadrupolar NMR are detailed and their applications to 27Al nucleus are illustrated. The potential of this technique is exemplified with some representative studies of relevance to mineral, biological, and organic aluminum-based systems.
Keywords:
27Al nucleus;
aluminum chemistry;
chemical shifts;
materials;
nuclear magnetic resonance;
organoaluminum;
quadrupolar relaxation;
scalar coupling;
spectroscopy
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