Far Infrared Laser Detector Based on Multi-Walled Carbon Nanotubes and Blend of (Polyaniline - Polymethyl Methacrylate) Polymers with Methyl Blue Dye for Photoconductive Applications

IF 0.4 Q4 NANOSCIENCE & NANOTECHNOLOGY Nano Hybrids and Composites Pub Date : 2021-10-11 DOI:10.4028/www.scientific.net/NHC.33.93
W. R. Saleh, S. Hassan, S. Y. Al-Dabagh, M. Marwa
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Abstract

Infrared photoconductive detectors working in the far-infrared region and room temperature were fabricated. The detectors were fabricated using three types of carbon nanotubes (CNTs); MWCNTs, COOH-MWCNTs, and short-MWCNTs. The carbon nontubes suspension is deposited by dip coating and drop–casting techniques to prepare thin films of CNTs. These films were deposited on porous silicon (PSi) substrates of n-type Si. The I-V characteristics and the figures of merit of the fabricated detectors were measured at a forward bias voltage of 3 and 5 volts as well as at dark and under illumination by IR radiation from a CO2 laser of 10.6 μm wavelengths and power of 2.2 W. The responsivity and figures of merit of the photoconductive detector are improved by coating the MWCNTs films with a thin layer of a blend (polyaniline - polymethyl methacrylate) polymer with methylene blue dye. The coated MWCNTs films showed better performances, so this type of coating can be considered as a surface treatment of the detector film, which highly increased the responsivity and specific detectivity of the fabricated IR laser detector-based MWCNTs. The photocurrent response for the coated films was increased about 25 times than that for uncoated films. The results proved the role of the polymer in the enhancement of the performance of the IR photoconductive detectors. Keywords: Carbon nanotubes, Infrared detector, Polyaniline polymer, Polymethyl methacrylate polymer, Methyl Blue dye.
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基于多壁碳纳米管和(聚苯胺-聚甲基丙烯酸甲酯)聚合物与甲基蓝染料共混物的光导远红外激光探测器
制作了工作在远红外区和室温下的红外光导探测器。探测器采用三种类型的碳纳米管(CNTs)制备;MWCNTs、COOH-MWCNTs和short-MWCNTs。采用浸镀和滴铸两种方法制备了碳纳米管悬浮液。这些薄膜被沉积在多孔硅(PSi)的n型Si衬底上。在正向偏置电压为3和5伏、黑暗和波长为10.6 μm、功率为2.2 W的CO2激光的红外照射下,测量了所制备的探测器的I-V特性和优值。通过在MWCNTs薄膜上涂覆一层亚甲基蓝染料(聚苯胺-聚甲基丙烯酸甲酯)聚合物,提高了光导检测器的响应率和性能指标。涂层后的MWCNTs薄膜表现出更好的性能,因此这种涂层可以看作是探测器薄膜的表面处理,大大提高了制备的红外激光探测器MWCNTs的响应率和比探测率。涂覆薄膜的光电流响应比未涂覆薄膜提高了约25倍。结果证明了聚合物对红外光导探测器性能的增强作用。关键词:碳纳米管,红外探测器,聚苯胺聚合物,聚甲基丙烯酸甲酯聚合物,甲基蓝染料
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Nano Hybrids and Composites
Nano Hybrids and Composites NANOSCIENCE & NANOTECHNOLOGY-
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