Synthesis and X-ray crystal structure of (1S,3R,4S,1′S)-4-methyl-3-triphenyl-pnosphonium-1-[1′-methyl(methyiphenyl)]-2-hydrido-2-borazetidinium bromide—the first example of a four-membered C–B–N–C heterocycle

B. Booth, N. Lawrence, R. Pritchard, Humayan S. Rashid
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引用次数: 2

Abstract

The title compound and related derivatives are synthesised from enamino(triphenyl)phosphonium salts and borane, and converted into β-aminophosphonium salts and β-aminophosphine oxides containing two chiral centres.
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(1S,3R,4S, 1S)-4-甲基-3-三苯基-膦-1-[1 ' -甲基(甲苯基)]-2-羟基-2-硼氮杂环的合成及x射线晶体结构
标题化合物和相关衍生物由对氨基(三苯基)磷盐和硼烷合成,并转化为含有两个手性中心的β-氨基膦盐和β-氨基膦氧化物。
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