{"title":"The mass spectra of crown ethers: The effects of preferred secondary structures on fragmentation patterns","authors":"Y.C. Lee, Alexander I. Popov, John Allison","doi":"10.1016/0020-7381(83)85012-8","DOIUrl":null,"url":null,"abstract":"<div><p>The 70 eV mass spectra of unsubstituted cyclic polyethers, “crown ethers”, from 12-crown-4 (12 membered ring) to 21-crown-7 (21 membered ring) are reported. These compounds exhibit very nearly identical spectra. Preferred secondary structures for these compounds from solution studies are used to explain specific unimolecular rearrangements; that is, the mass spectra of these “three dimensional molecules” is discussed.</p></div>","PeriodicalId":13998,"journal":{"name":"International Journal of Mass Spectrometry and Ion Physics","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1983-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-7381(83)85012-8","citationCount":"25","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Mass Spectrometry and Ion Physics","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020738183850128","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 25
Abstract
The 70 eV mass spectra of unsubstituted cyclic polyethers, “crown ethers”, from 12-crown-4 (12 membered ring) to 21-crown-7 (21 membered ring) are reported. These compounds exhibit very nearly identical spectra. Preferred secondary structures for these compounds from solution studies are used to explain specific unimolecular rearrangements; that is, the mass spectra of these “three dimensional molecules” is discussed.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
