Functionalisation of [Mo6O19]2– with aromatic amines: synthesis and structure of a hexamolybdate building block with linear difunctionality

W. Clegg, R. Errington, K. Fraser, S. Holmes, A. Schäfer
{"title":"Functionalisation of [Mo6O19]2– with aromatic amines: synthesis and structure of a hexamolybdate building block with linear difunctionality","authors":"W. Clegg, R. Errington, K. Fraser, S. Holmes, A. Schäfer","doi":"10.1039/C39950000455","DOIUrl":null,"url":null,"abstract":"In reactions between the hexamolybdate [Mo6O19]2– and 1,4-diaminobenzene, terminal oxides are replaced by 4-aminophenylimido ligands and the first structurally characterised polyoxometallate to contain functionalised organoimido ligands, (Bun4)2[Mo6O17(NC6H4NH2)2]5, is also the first example of a trans-bis(imido) derivative; further condensation also occurs to yield species in which hexamolybdate units are linked by 1,4-phenylenediimido bridges.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"184 1","pages":"455-456"},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"87","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950000455","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 87

Abstract

In reactions between the hexamolybdate [Mo6O19]2– and 1,4-diaminobenzene, terminal oxides are replaced by 4-aminophenylimido ligands and the first structurally characterised polyoxometallate to contain functionalised organoimido ligands, (Bun4)2[Mo6O17(NC6H4NH2)2]5, is also the first example of a trans-bis(imido) derivative; further condensation also occurs to yield species in which hexamolybdate units are linked by 1,4-phenylenediimido bridges.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
[Mo6O19]2 -与芳香胺的功能化:具有线性二官能性的六钼酸盐构建块的合成和结构
在六钼酸盐[Mo6O19]2 -和1,4-二氨基苯之间的反应中,末端氧化物被4-氨基苯基配体取代,并且第一个结构上表征的含有功能化有机亚胺配体的多金属氧酸盐(Bun4)2[Mo6O17(NC6H4NH2)2]5也是反式双(亚胺)衍生物的第一个例子;进一步的缩合也发生在六钼酸盐单元由1,4-苯二胺桥连接的产物中。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
自引率
0.00%
发文量
0
审稿时长
2 months
期刊最新文献
Competing pathways in the phototransposition of pyrazoles Total synthesis of (+)-polyoxin J Symmetric bis-benzimidazoles, a new class of sequence-selective DNA-binding molecules Aldehydes and Ketones as Dipolarophiles. Application to the Synthesis of Oxapenams Chemoselective platinum(0)-catalysed hydrophosphination of ethyl acrylate
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1