Self‐repairable, high‐uniform conductive‐bridge random access memory based on amorphous NbSe2

SmartMat Pub Date : 2023-08-08 DOI:10.1002/smm2.1240
B. Lu, Dunan Hu, Ruqi Yang, Jigang Du, Lingxiang Hu, Siqin Li, Fengzhi Wang, Jingyun Huang, Pingwei Liu, F. Zhuge, Yutian Zeng, Zhuolin Ye, Jianguo Lu
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引用次数: 1

Abstract

Conductive‐bridge random access memory (CBRAM) emerges as a promising candidate for next‐generation memory and storage device. However, CBRAMs are prone to degenerate and fail during electrochemical metallization processes. To address this issue, herein we propose a self‐repairability strategy for CBRAMs. Amorphous NbSe2 was designed as the resistive switching layer, with Cu and Au as the top and bottom electrodes, respectively. The NbSe2 CBRAMs demonstrate exceptional cycle‐to‐cycle and device‐to‐device uniformity, with forming‐free and compliance current‐free resistive switching characteristics, low‐operation voltage, and competitive endurance and retention performance. Most importantly, the self‐repairable behavior is discovered for the first time in CBRAM. The device after failure can recover its performance to the initially normal state by operating with a slightly large reset voltage. The existence of Cu conductive filament and excellent controllability of Cu migration in the NbSe2 switching layer has been revealed by a designed broken‐down point approach, which is responsible for the self‐repairable behavior of NbSe2 CBRAMs. Our self‐repairable and high‐uniform amorphous NbSe2 CBRAM may open the door to the development of memory and storage devices in the future.
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基于非晶NbSe2的自修复、高均匀导电桥随机存取存储器
导电桥随机存取存储器(CBRAM)是下一代存储器和存储器件的一个很有前途的候选者。然而,在电化学金属化过程中,cbram容易发生退化和失效。为了解决这一问题,本文提出了一种cbram的自我修复策略。非晶NbSe2被设计为电阻开关层,Cu和Au分别作为上电极和下电极。NbSe2 cbram具有优异的周期到周期和器件到器件的均匀性,具有无成形和无电流的电阻开关特性,低工作电压,具有竞争力的耐用性和保持性能。最重要的是,在CBRAM中首次发现了自修复行为。故障后的器件可以通过稍大的复位电压运行,使其性能恢复到最初的正常状态。通过设计的击穿点方法揭示了Cu导电丝的存在和Cu在NbSe2开关层中迁移的优异可控性,这是NbSe2 cbram自修复行为的原因。我们的自修复和高均匀非晶NbSe2 CBRAM可能为未来存储器和存储设备的发展打开大门。
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