Time-domain spectroscopy of spin state transition in polymeric spin crossover compounds

B. Viquerat, J. Degert, M. Tondusson, J. Létard, C. Mauriac, E. Freysz
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引用次数: 1

Abstract

We have measured the evolution of the THz spectrum of polymeric iron(II) spin crossover compounds within the Low-Spin/High-Spin thermal hysteresis loop in the ∼0.6–6 THz frequency range. This study enabled to evidence the large variations of both the refractive optical index and the absorption that occur during the spin state phase transition.
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高分子自旋交叉化合物中自旋态跃迁的时域光谱
我们测量了聚合物铁(II)自旋交叉化合物在低自旋/高自旋热滞后回路中在~ 0.6-6太赫兹频率范围内的太赫兹谱的演变。该研究证明了自旋态相变期间发生的折射率和吸收的大变化。
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