Synthesis, Crystal Structure, and Luminescent Property of One 3D Pillared-Layer Complex Based on 5-Methoxyisophthalate and 1,4-Bis(imidazol-1-yl)-butane Ligands
{"title":"Synthesis, Crystal Structure, and Luminescent Property of One 3D Pillared-Layer Complex Based on 5-Methoxyisophthalate and 1,4-Bis(imidazol-1-yl)-butane Ligands","authors":"Huarui Wang, Jian-ge Wang","doi":"10.1080/15533174.2014.988800","DOIUrl":null,"url":null,"abstract":"One three-dimensional (3D) coordination polymer, [Zn(L)(bimb)0.5]n (1) (L = 5-methoxyisophthalate, bimb = 1,4-bis(imidazol-1-yl)-butane), was synthesized and studied by elemental analysis, IR spectroscopy, and X-ray crystallography. This complex belongs to monoclinic system with space group P21/n, and exhibits a 3D (3,4)-connected net. In the structure of 1, the L ligand connects Zn(II) ions giving rise to a 2D helical layer. Adjacent ones are joined by bimb pillars to generate a novel 3D pillared-layer framework. Furthermore, luminescent property of 1 was also investigated.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2016-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2014.988800","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
Abstract
One three-dimensional (3D) coordination polymer, [Zn(L)(bimb)0.5]n (1) (L = 5-methoxyisophthalate, bimb = 1,4-bis(imidazol-1-yl)-butane), was synthesized and studied by elemental analysis, IR spectroscopy, and X-ray crystallography. This complex belongs to monoclinic system with space group P21/n, and exhibits a 3D (3,4)-connected net. In the structure of 1, the L ligand connects Zn(II) ions giving rise to a 2D helical layer. Adjacent ones are joined by bimb pillars to generate a novel 3D pillared-layer framework. Furthermore, luminescent property of 1 was also investigated.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
