Achieving the Carbon-Neutral Production of Magnesia and Silica Products Using a HCl-Based Process in Serpentine Feedstock

David Konlechner, Gregor Kappacher
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Abstract

Magnesia is mainly produced from carbonate sources (magnesite (MgCO3)), and seawater brines (MgCl2). The calcination of magnesite and the precipitation of brine using quicklime (CaO) are processes that have significant CO2 footprints, even before considering the burning of hydrocarbons required to meet the energy demand. There are also significant amounts of silica-based magnesia raw materials available worldwide, such as serpentine, dunite, and olivine. It is possible to produce synthetic MgO of high purity using a HCl-based process. HCl can be fully recycled and reused. If a carbon-neutral heating source such as electricity, synthetic fuel, or plasma is used for the pyrohydrolysis process, the result is the production of MgO via a carbon-neutral process.
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在蛇纹石原料中采用盐酸法实现镁和硅产品的碳中性生产
镁主要产自碳酸盐(菱镁矿(MgCO3))和海水卤水(MgCl2)。菱镁矿的煅烧和使用生石灰(CaO)沉淀卤水的过程具有显著的二氧化碳足迹,甚至在考虑燃烧所需的碳氢化合物以满足能源需求之前。世界上也有大量的硅基氧化镁原料,如蛇纹石、白云石和橄榄石。用盐酸法合成高纯度氧化镁是可能的。盐酸可以完全回收再利用。如果在热水解过程中使用碳中性热源,如电、合成燃料或等离子体,则结果是通过碳中性过程生产MgO。
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