Spectroscopic Characterization of Bentonite

T. RavindraReddy, S. Kaneko, T. Endo, S. LakshmiReddy
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引用次数: 37

Abstract

A light yellow colored bentonite clay mineral obtained from India is studied. X ray diffraction (XRD) studies are suggesting that Fe2O3, Al2O3, quartz and Ca bentonite phases are present in the compound. Ca-bentonite is the major constituent and its unit cell is monoclinic with a=5.16, b=8.798, c=9.347A and β=100.46°. Internal structure studied using Transimission electron microscope (TEM) suggests that the clay consists of iron oxide, aluminium oxide, quartz, Ca bentonite. Tetrahedral and octahedral layers are present. Fe3+ is present in the location of Al3+ in the unit cell of Ca-bentonite. Electron paramagnetic resonance (EPR) results indicate that the unit cell of the crystal contains Fe(III), and its g values are found to be 4.19 and 2.13. IR studies are indicating that the presence of silicate and hydroxyl anions as ligands. Nonlinear optical measurements are indicating that the compound is having good potential applications in laser safety devices.
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膨润土的光谱表征
研究了一种产自印度的淡黄色膨润土粘土矿物。X射线衍射(XRD)研究表明,化合物中存在Fe2O3、Al2O3、石英和Ca膨润土相。ca -膨润土为主要成分,其单晶胞为单斜晶胞,a=5.16, b=8.798, c=9.347A, β=100.46°。透射电镜(TEM)对粘土的内部结构进行了研究,表明粘土由氧化铁、氧化铝、石英、钙膨润土组成。存在四面体和八面体层。Fe3+存在于钙基膨润土中Al3+的位置。电子顺磁共振(EPR)结果表明,晶体的晶胞中含有Fe(III),其g值分别为4.19和2.13。红外光谱研究表明,硅酸盐和羟基阴离子作为配体存在。非线性光学测量结果表明,该化合物在激光安全器件中具有良好的应用前景。
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