TRANSESTERIFICATION OF PALM OIL USING THE TiO2/nano-MONMORILLORITE (nano-MMT) COMPOSITE CATALYST FROM ACEH TAMIANG BENTONITE IN THE PRODUCTION OF BIODIESEL

T. A. Fadlly, Ida Ratna Nila, Nirmala Sari
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Abstract

Transesterification of palm oil using a TiO 2 /nano-Monmorillorite (nano-MMT) composite catalyst from Aceh Tamiang bentonite in Biodiesel production has been carried out. Biodiesel is bioenergy obtained from vegetable oils, animal fats, microorganisms, and plants. This is alternative energy to replace fossil fuels, especially diesel oil. Biodiesel is proven to be more environmentally friendly in reducing hydrocarbon and sulfur emissions. In this study, TiO 2 will be composited with nano-MMT using the solid-state method and analyzed using XRD. Both of these materials are used as catalysts for biodiesel production. The transesterification process will be used in the production of biodiesel, where the molar ratio of palm oil to methanol is 1:12. TiO 2 /nano-MMT composite catalyst will be varied (2 and 4 grams). Biodiesel samples will be analyzed using GC-MS. The results obtained show that the TiO 2 /nano-MMT composite catalyst from Aceh Tamiang bentonite can convert Fatty Acid Methyl Ester (FAME) from palm oil. The 2 grams of the composite catalyst produced biodiesel of 89.38% and 4 grams of 64.88%.
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亚齐膨润土中TiO2/纳米蒙脱土复合催化剂催化棕榈油酯交换制备生物柴油
以亚齐膨润土为原料,采用tio2 /纳米蒙脱土(纳米mmt)复合催化剂对棕榈油进行了酯交换反应。生物柴油是从植物油、动物脂肪、微生物和植物中获得的生物能源。这是一种替代化石燃料的能源,尤其是柴油。事实证明,生物柴油在减少碳氢化合物和硫的排放方面更环保。本研究将采用固相法将tio2与纳米mmt复合,并用XRD对其进行分析。这两种材料都被用作生物柴油生产的催化剂。酯交换过程将用于生产生物柴油,其中棕榈油与甲醇的摩尔比为1:12。tio2 /纳米- mmt复合催化剂将变化(2克和4克)。生物柴油样品将使用GC-MS进行分析。结果表明,以亚齐膨润土为原料制备的tio2 /纳米mmt复合催化剂可催化棕榈油中脂肪酸甲酯(FAME)的转化。2 g复合催化剂产率为89.38%,4 g复合催化剂产率为64.88%。
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