Chiral inclusion crystals constructed with achiral host and achiral guest molecules.

Enantiomer Pub Date : 2002-03-01 DOI:10.1080/10242430212198
F. Toda
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引用次数: 2

Abstract

Achiral molecules of tetrakis(p-bromophenyl)ethylene and 2,3,6,7,10,11-hexahydroxy triphenylene were found to arrange in a chiral form in their inclusion crystal with an achiral guest molecule. The chiral arrangement of these achiral molecules was studied by X-ray analysis and CD spectral measurement in the solid state.
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由非手性宿主和非手性客体分子构建的手性包合晶体。
发现四对溴苯基乙烯和2,3,6,7,10,11-六羟基三苯的非手性分子与非手性客体分子在包涵晶体中以手性形式排列。通过x射线分析和CD光谱测量,研究了这些非手性分子在固体状态下的手性排列。
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