ELECTROCHEMICAL PERFORMANCE OF COMPOST EXTRACTS CONTAINING N,N,N',N'-TETRAMETHYLPHENYLENEDIAMINE (TMPD)

S. Elaigwu, A. U. Awode, B. Tukura
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Abstract

Composting is a well-known practice for valorizing organic waste materials into useful product. Its use in the management of soils, which are contaminated with organic compounds has been widely studied and reported. Nevertheless, the present approach of analysing the organic compounds and its degradation products using GC-MS is costly. Hence, the need for an alternative analytical screening technique which is less expensive and fast, when compared with the GC-MS analysis. As a probable alternative approach, the cyclic voltammetry of compost extracts containing N,N,N',N'-Tetramethylphenylenediamine (TMPD) is described in this study. The result of the study, however revealed that cyclic voltammetry could neither detect the presence of the TMPD nor its degradation products in any of the compost extract. This might have resulted from the strong and complex matrix of the compost which prevented the oxidation of the TMPD in the compost extract.
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n, n, n′,n′-四甲基苯二胺(tmpd)复合提取物的电化学性能
堆肥是一种众所周知的将有机废物转化为有用产品的做法。它在被有机化合物污染的土壤管理中的应用已被广泛研究和报道。然而,目前使用GC-MS分析有机化合物及其降解产物的方法是昂贵的。因此,与气相色谱-质谱分析相比,需要一种更便宜、更快速的替代分析筛选技术。作为一种可能的替代方法,本研究描述了含有N,N,N',N'-四甲基苯基二胺(TMPD)的堆肥提取物的循环伏安法。然而,研究结果表明,循环伏安法既不能检测到TMPD的存在,也不能在任何堆肥提取物中检测到其降解产物。这可能是由于堆肥的强而复杂的基质阻止了堆肥提取物中TMPD的氧化。
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