{"title":"γ-radiolysis of myo-inositol hexasulphate (free acid) in aqueous solution","authors":"M. Balakrishnan, W.J. Criddle, B.J. Jones","doi":"10.1016/0020-7055(76)90021-8","DOIUrl":null,"url":null,"abstract":"<div><p>The effects of <em>γ</em>-radiation on aqueous solutions of myo-inositol hexasulphate in the free acid form have been studied. The results have been explained on the basis of radical initiated chain processes which lead to the observed high <em>G</em>-values for the ultimate inorganic product namely the sulphate ion and to low hydrogen peroxide yields. In addition, steady-state competition procedures and pulse radiolysis experiments show that the reaction between the OH and the substrate is slow.</p></div>","PeriodicalId":100688,"journal":{"name":"International Journal for Radiation Physics and Chemistry","volume":"8 5","pages":"Pages 549-553"},"PeriodicalIF":0.0000,"publicationDate":"1976-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-7055(76)90021-8","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal for Radiation Physics and Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020705576900218","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
Abstract
The effects of γ-radiation on aqueous solutions of myo-inositol hexasulphate in the free acid form have been studied. The results have been explained on the basis of radical initiated chain processes which lead to the observed high G-values for the ultimate inorganic product namely the sulphate ion and to low hydrogen peroxide yields. In addition, steady-state competition procedures and pulse radiolysis experiments show that the reaction between the OH and the substrate is slow.
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