Verwendung von Metalloxyd-Schichten mit Plasmakontakt zur Energiewandlung

M. Hartl
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Abstract

The photovoltaic effect in oxide layers on so-called valve metalls (Al, Ta, Zr, etc.) can be used on principle also for the direct conversion of energy from radioactive particles (α and β) into electrical energy. It can be expected that the resistivity of these oxide layers against radiation damages because of their usually amorphous structure is higher compared with p-n junctions in monocrystalline semiconductors. Since the photovoltaic effect in these oxide layers is not connected with a metallic (or electrolytic) sandwich contacting it is proposed to use an ionized gas as counter electrode, this gas being possibly ionized by radiactive radiation itself. This method was qualitatively investigated by β-irradiation (Tritium) of Ta2O5-layers produced by anodizing.

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氧化金属离子与等离子气体相溶、变能
所谓的阀门金属(Al, Ta, Zr等)的氧化层中的光伏效应原则上也可用于将放射性粒子(α和β)的能量直接转换为电能。可以预期,由于这些氧化层通常具有非晶结构,因此其抗辐射损伤的电阻率高于单晶半导体中的pn结。由于这些氧化层中的光伏效应与金属(或电解)夹层接触无关,因此建议使用电离气体作为对电极,该气体可能被放射性辐射本身电离。采用β-氚照射氧化法制备的ta2o5层,对该方法进行了定性研究。
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