Behaviour of hydrogen and silver–silver chloride electrodes in acetonitrile solutions

H. P. Bennetto, J. Spitzer
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Abstract

Under suitable conditions, silver–silver chloride and hydrogen electrodes operate reversibly in acetonitrile–methanol mixtures; the free energy of transfer of H+Cl– from methanol to acetonitrile–methanol (40:60) has been determined from the results of cell measurements.
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氢和银-氯化银电极在乙腈溶液中的行为
在合适的条件下,银-氯化银和氢电极在乙腈-甲醇混合物中可逆地工作;根据电池测量结果确定了H+Cl -从甲醇到乙腈-甲醇(40:60)转移的自由能。
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