The Role of Surface Texture on the Corrosion Fatigue Behavior of High Alloyed Stainless Steel Exposed to Saline Aquifer Water Environment

A. Pfennig, M. Wolf, A. Kranzmann
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引用次数: 4

Abstract

Corrosion fatigue specimen with different surfaces (technical surfaces after machining and polished surfaces) of high alloyed martensitic stainless steel X46Cr13 (1.4043) and duplex stai nless steel X2CrNiMoN22 3 2 (1.4462) were compared at load amplitudes from 175 MPa to 325 MPa in the geothermal brine of the N orthern German Basin at 98 °C. Surface corrosion layers and pits reveal carbonate corrosion products on the surface such as FeCO 3 and FeOOH as the main precipitation phases with no dependence on the original surface roughness . At high stress amplitudes above 275 MPa technical surfaces (P50% at σa 300 MPa=5 × 10 5 ) resulted in more cycles to failure than polished (P50% at σa 300 MPa=1.5 × 10 5 ). The greater slope coefficient for technical surfaces k = 19.006 compared to polished surfaces k =8.78 demonstrate s earlier failure at given stress amplitude σa .
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表面织构对含盐含水层水环境中高合金不锈钢腐蚀疲劳行为的影响
采用高合金马氏体不锈钢X46Cr13(1.4043)和双相不锈钢x2crnimon2232(1.4462)的不同表面(加工后的工艺表面和抛光后的表面),在德国北部盆地地热盐水中,在98℃下175 ~ 325 MPa的载荷幅值下进行了腐蚀疲劳试样的比较。表面腐蚀层和蚀坑以FeCO 3和FeOOH等碳酸盐腐蚀产物为主要析出相,与原始表面粗糙度无关。在275 MPa以上的高应力幅值下,技术表面(σa 300 MPa=5 × 10 5时的P50%)比抛光表面(σa 300 MPa=1.5 × 10 5时的P50%)的失效循环次数更多。在给定应力幅σa下,技术面k = 19.006的斜率系数大于抛光面k =8.78的斜率系数。
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