Политермический разрез SnAs–P тройной системы Sn–As–P

Kondensirovannye sredy i mezhfaznye granitsy = Condensed Matter and Interphases Pub Date : 2019-06-14 DOI:10.17308/KCMF.2019.21/766

Tatiana P. Sushkova, Aleksandra V. Sheveljuhina, G. V. Semenova, Elena Yu. Proskurina

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Phosphorus-Based Alloy Materials for Advanced Potassium-Ion Battery Anode // Am. Chem. Soc., 2017, v. 139(9), pp. 3316–3319. https://doi.org/10.1021/jacs.6b12185 \nLiu S., Zhang H., Xu L., Ma L., Chen X. Solvothermal preparation of tin phosphide as a long-life anode for advanced lithium and sodium ion batteries // of Power Sources, 2016, v. 304, pp. 346–353. https://doi.org/10.1016/j.jpowsour.2015.11.056 \nZhang W., Pang W., Sencadas V., Guo Z. Understanding High-Energy-Density Sn4P3 Anodes for Potassium-Ion Batteries // Joule, 2018, v. 2(8), pp. 1534–1547. https://doi.org/10.1016/j.joule.2018.04022 \nLan D., Wang W., Shi L., Huang Y., Hu L., Li Q. Phase pure Sn4P3 nanotops by solution-liquid-solid growth for anode application in sodium ion batteries // Mater. Chem. A, 2017, v. 5, pp. 5791–5796. https://doi.org/10.1039/C6TA10685D \nMogensen R., Maibach J., Naylor A. J., Younesi R. Capacity fading mechanism of tin phosphide anodes in sodium-ion batteries // Dalton Trans., 2018, v. 47, pp. 10752–10758. https://doi.org/10.1039/c8dt01068d \nKamali A. R., Fray D. J. Tin-based materials as advanced anode materials for lithium ion batteries: a review // Adv. Mater. Sci., 2011, v. 27, pp. 14–24. URL: http://194.226.210.10/e-journals/RAMS/no12711/kamali.pdf \nKovnir K. A., Kolen’ko Y. V., Baranov A. I., Neira I. S., Sobolev A. V., Yoshimura M., Presniakov I. A., Shevelkov A. V. Sn4As3 revisited: Solvothermal synthesis and crystal and electronic structure // Journal of Solid State Chemistry, 2009, v. 182(5), pp. 630–639. https://doi.org/10.1016/j.jssc.2008.12.007 \nSemenova G. V., Kononova E. Yu., Sushkova T. P. Polythermal section Sn4P3 – Sn4As3 // Russian J. of Inorganic Chemistry, 2013, v. 58 (9), pp. 1242–1245. https://doi.org/10.7868/S0044457X13090201 \nSushkova T. P, Semenova G. V., Naumov A. V., Proskurina E. Yu. Solid solutions in the system Sn-As-P // Bulletin of VSU. Series: Chemistry. Biology. Pharmacy, 2017, v. 3, pp. 30–36. URL: http://www. vestnik.vsu.ru/pdf/chembio/2017/03/2017-03-05.pdf \nSemenova G. V., Sushkova T. P, Tarasova L. A., Proskurina E. Yu. Phase equilibria in a Sn-As-P system with a tin concentration less than 50 mol. % // Condensed Matter and Interphases, 2017, v. 19(3), pp. 408–416. https://doi.org/10.17308/kcmf.2017.19/218 \nSemenova G. V., Sushkova T. P., Zinchenko E. N., Yakunin S. V. Solubility of phosphorus in tin monoarsenide // Condensed Matter and Interphases, 2018, v. 20(4), pp. 644-649. https://doi.org/10.17308/kcmf.2018.20/639 \nSemenova G. V., Goncharov E. G. Solid Solutions Involving Elements of the Fifth Group. – Мoscow, MFTI Publ., 2000, 160 p. (in Russ.) \nOkamoto H. Phase diagrams for binary alloys, Second Edition. Materials Park, OH.: ASM International, 2010, 810 р. URL: https://www.asminternational. org/...pdf/c36eeb4e-d6ec-4804-b319-e5b0600ea65d \nShirotani , Shiba S., Takemura K., Shimomura О., Yagi Т. Pressure-induced phase transitions of phosphorus-arsenic alloys // Physica B: Condensed Matter, 1993, v. 190, pp. 169–176. https://doi.org/10.1016/0921-4526(93)90462-F \nArita M., Kamo K. Measurement of vapor pressure of phosphorus over Sn-P alloys by dew point method // Jpn. Inst. Met., 1985, v. 26(4), pp. 242–250. https://doi.org/10.2320/matertrans1960.26.242 \nZavrazhnov A. Yu., Semenova G. V., Proskurina E. Yu., Sushkova T. P. Phase diagram of the Sn–P system // Thermal Analysis and Calorimetry, 2018, v. 134(1), pp. 475–481. https://doi.orgh/10.1007/s10973-018-7123-0 \nGokcen N. A. The As-Sn (Arsenic-Tin) system // Bulletin of alloy phase diagrams, 1990, v. 11(3), pp. 271–278. https://doi.org/10.1007/BF03029298 \n","PeriodicalId":17879,"journal":{"name":"Kondensirovannye sredy i mezhfaznye granitsy = Condensed Matter and Interphases","volume":"69 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2019-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Kondensirovannye sredy i mezhfaznye granitsy = Condensed Matter and Interphases","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.17308/KCMF.2019.21/766","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

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Abstract

Проведено исследование фазовых равновесий в тройной системе Sn–As–P в области высокой концентрации летучих компонентов. Методами рентгенофазового и дифференциального термического анализа изучены сплавы политермического разреза SnAs–P. Показано, что растворимость фосфора в моноарсениде олова в направлении этого разреза менее 0.05 мол.д. фосфора. Построена Т-х диаграмма политермического сечения SnAs–Р. Наличие на Т-х диаграмме горизонтали при температуре 827±2 К соответствует реализации в системе Sn–As–P нонвариантного перитектического равновесия L + (d) ↔ b + g , где (d), b и g – трехкомпонентные твердые растворы на основе As1-xPx, SnAs и SnP3 соответственно REFERENCES Zhang W., Mao J., Li S., Chen Z., Guo Z. Phosphorus-Based Alloy Materials for Advanced Potassium-Ion Battery Anode // Am. Chem. Soc., 2017, v. 139(9), pp. 3316–3319. https://doi.org/10.1021/jacs.6b12185 Liu S., Zhang H., Xu L., Ma L., Chen X. Solvothermal preparation of tin phosphide as a long-life anode for advanced lithium and sodium ion batteries // of Power Sources, 2016, v. 304, pp. 346–353. https://doi.org/10.1016/j.jpowsour.2015.11.056 Zhang W., Pang W., Sencadas V., Guo Z. Understanding High-Energy-Density Sn4P3 Anodes for Potassium-Ion Batteries // Joule, 2018, v. 2(8), pp. 1534–1547. https://doi.org/10.1016/j.joule.2018.04022 Lan D., Wang W., Shi L., Huang Y., Hu L., Li Q. Phase pure Sn4P3 nanotops by solution-liquid-solid growth for anode application in sodium ion batteries // Mater. Chem. A, 2017, v. 5, pp. 5791–5796. https://doi.org/10.1039/C6TA10685D Mogensen R., Maibach J., Naylor A. J., Younesi R. Capacity fading mechanism of tin phosphide anodes in sodium-ion batteries // Dalton Trans., 2018, v. 47, pp. 10752–10758. https://doi.org/10.1039/c8dt01068d Kamali A. R., Fray D. J. Tin-based materials as advanced anode materials for lithium ion batteries: a review // Adv. Mater. Sci., 2011, v. 27, pp. 14–24. URL: http://194.226.210.10/e-journals/RAMS/no12711/kamali.pdf Kovnir K. A., Kolen’ko Y. V., Baranov A. I., Neira I. S., Sobolev A. V., Yoshimura M., Presniakov I. A., Shevelkov A. V. Sn4As3 revisited: Solvothermal synthesis and crystal and electronic structure // Journal of Solid State Chemistry, 2009, v. 182(5), pp. 630–639. https://doi.org/10.1016/j.jssc.2008.12.007 Semenova G. V., Kononova E. Yu., Sushkova T. P. Polythermal section Sn4P3 – Sn4As3 // Russian J. of Inorganic Chemistry, 2013, v. 58 (9), pp. 1242–1245. https://doi.org/10.7868/S0044457X13090201 Sushkova T. P, Semenova G. V., Naumov A. V., Proskurina E. Yu. Solid solutions in the system Sn-As-P // Bulletin of VSU. Series: Chemistry. Biology. Pharmacy, 2017, v. 3, pp. 30–36. URL: http://www. vestnik.vsu.ru/pdf/chembio/2017/03/2017-03-05.pdf Semenova G. V., Sushkova T. P, Tarasova L. A., Proskurina E. Yu. Phase equilibria in a Sn-As-P system with a tin concentration less than 50 mol. % // Condensed Matter and Interphases, 2017, v. 19(3), pp. 408–416. https://doi.org/10.17308/kcmf.2017.19/218 Semenova G. V., Sushkova T. P., Zinchenko E. N., Yakunin S. V. Solubility of phosphorus in tin monoarsenide // Condensed Matter and Interphases, 2018, v. 20(4), pp. 644-649. https://doi.org/10.17308/kcmf.2018.20/639 Semenova G. V., Goncharov E. G. Solid Solutions Involving Elements of the Fifth Group. – Мoscow, MFTI Publ., 2000, 160 p. (in Russ.) Okamoto H. Phase diagrams for binary alloys, Second Edition. Materials Park, OH.: ASM International, 2010, 810 р. URL: https://www.asminternational. org/...pdf/c36eeb4e-d6ec-4804-b319-e5b0600ea65d Shirotani , Shiba S., Takemura K., Shimomura О., Yagi Т. Pressure-induced phase transitions of phosphorus-arsenic alloys // Physica B: Condensed Matter, 1993, v. 190, pp. 169–176. https://doi.org/10.1016/0921-4526(93)90462-F Arita M., Kamo K. Measurement of vapor pressure of phosphorus over Sn-P alloys by dew point method // Jpn. Inst. Met., 1985, v. 26(4), pp. 242–250. https://doi.org/10.2320/matertrans1960.26.242 Zavrazhnov A. Yu., Semenova G. V., Proskurina E. Yu., Sushkova T. P. Phase diagram of the Sn–P system // Thermal Analysis and Calorimetry, 2018, v. 134(1), pp. 475–481. https://doi.orgh/10.1007/s10973-018-7123-0 Gokcen N. A. The As-Sn (Arsenic-Tin) system // Bulletin of alloy phase diagrams, 1990, v. 11(3), pp. 271–278. https://doi.org/10.1007/BF03029298

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SnAs -三重系统Sn - As - P的多热断面

在Sn - As - P三重系统中进行了一项关于高挥发元件浓度的相平衡研究。x射线和微分热分析分析了SnAs - P多热切口的合金。在锡的单链中，磷的溶解度小于0.05兆。磷。它创建了SnAs - r的多热截面t - x图。化学赞。Soc。2017年，v139 (9)， pp, 3316 - 3319。https://doi.org/10.1021/jacs.6b12185 (S, Zhang H。许志永Ma L。L。Chen x Solvothermal preparation of tin phosphide as a long - life anode for advanced锂and市场ion batteries / 2016 / of Power字段304,v . pp - 346 - 353。https://doi.org/10.1016/j.jpowsour.2015.11.056 Zhang W, W, Pang。Sencadas V, Guo z Understanding High Energy -密度Sn4P3 Anodes for Potassium - Ion Batteries / / Joule 2018 V . 2 (8), pp 1534 - 1547。https://doi.org/10.1016/j.joule.2018.04022局域网D。W。Wang, Shi L黄Y。q, Hu L。Li, pure Sn4P3阶段nanotops by solution流质- solid的《for anode应用程序市场离子batteries / in /母校。化学赞。A, 2017, v5, pp, 5791, 5796。https://doi.org/10.1039/C6TA10685D Mogensen R, Naylor Maibach J·a·J。tin phosphide, Younesi R .衰落的机制最终of anodes in ion batteries /市场/博Trans。2018年，v47, pp, 10752 - 10758。https://doi.org/10.1039/c8dt01068d Kamali a . R . Fray d . j .基于Tin的材料as for advanced anode材料锂离子batteries: a review) / / Adv.母校。Sci。2011年，v27, pp, 14 - 24。URL: http://194.226.210.10/e-journals/RAMS/no12711/kamali.pdf Kovnir k A。Kolen 'ko y V Baranov A . I。,Neira一世S。A Sobolev V、Yoshimura M Presniakov一世A。A Shevelkov V . Sn4As3重访:Solvothermal synthesis and crystal and electronic结构/ / Journal of Solid State V . 182 Chemistry》,2009 (5)pp - 630 - 639。Kononova e . Yu https://doi.org/10.1016/j.jssc.2008.12.007 Semenova g . V。Sushkova T. P. P. Polythermal部分- Sn4P3 - Sn4As3 /俄罗斯化学，2013年，v58(9)， 1242 - 1245。https://doi.org/10.7868/S0044457X13090201 Sushkova t P Naumov Semenova g . V。a . V, Proskurina e . Yu。Sn-As-P // Bulletin VSU系统中的解决方案。Series: Chemistry》。生物学。Pharmacy, 2017, v3, pp, 30 - 36。URL ciencia。vestnik.vsu.ru / pdf / chembio 2017/03/2017 - 03 - 05.pdf Semenova g . V。Sushkova t P, e Tarasova l . A ., Proskurina Yu。在一个Sn-As-P系统中，有一个超过50个mol的步骤。https://doi.org/10.17308/kcmf.2017.19/218 Semenova g . V Sushkova t P。,Yakunin Zinchenko e N。s . V . Solubility tin monoarsenide / /由来已久Matter of phosphorus in and Interphases 2018, 20(4节),pp 644 - 649。https://doi.org/10.17308/kcmf.2018.20/639 Semenova g Goncharov V。e . g . Solid Solutions Involving《the Fifth Group元素。莫斯科，MFTI公共。2000年，160个pOkamoto H.第二版，binary alloys。物质公园，哦。: ASM International, 2010 810 URL: https://www.asminternational先生。奥格/.. pdfr . c36e66e66e66e66e666e666e666e662e662e662e662e662e662d Shirotani, Shimomura的，Shimomura的，Shimomura的，Shimomura的，Shimomura的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的，她的。https://doi.org/10.1016/0921-4526 (93) 90462 F Arita M,联合推出k (exposition of steam pressure of Sn - P alloys phosphorus over by dew point method / / Jpn。Inst Met。1985年，v26 (4)， pp 242 - 250。https://doi.org/10.2320/matertrans1960.26.242 Zavrazhnov a . Yu。Semenova g V, Proskurina e Yu。Sn的Sushkova T. P.阶段是P系统//和Calorimetry, 2018年，v134(1)， 475 - 481。https://doi.orgh/10.1007/s10973-018-7123-0 Gokcen n . a . The As - Sn (Arsenic Tin) system / / Bulletin of alloy图》,1990,v . 11(3)阶段,pp 271 - 278。https://doi.org/10.1007/BF03029298

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