Adsorption Characteristics of Banana Peel in the Removal of Dyes from Textile Effluent

M. Akter, F. Rahman, M. Abedin, S. Kabir
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引用次数: 18

Abstract

Disposal of reactive dye contaminants in surface waters causes serious health risks to the aquatic living bodies and populations adjacent to the polluted water sources. This study investigated the applicability of banana peels to remediate water contamination with reactive dyes used in the textile industry. A set of batch experiments was conducted using a standard dye solution to determine optimum adsorption parameters, and these parameters were used for the removal of dyes from actual wastewater. Fitting experimental data into the isotherm and kinetic models suggested monolayer dye adsorption with chemisorption rate-limiting step. The maximum adsorption found from modeling results was 28.8 mg/g. Fourier transformed infrared (FTIR) spectra revealed the existence of hydroxyl, amine and carboxylic groups, contributing to high adsorption of dye molecules onto the adsorbent surface. About 93% of the dyes from the standard solution were removed at optimum conditions (pH—7.0, initial dye concentration—100 mg/L, contact time—60 min, and adsorbent dose—0.5 g) while this value was 84.2% for industrial textile wastewater. This difference was mainly attributed to the composition difference between the solutions. However, the removal efficiency for actual wastewater is still significant, indicating the high potentiality of banana peel removing dyes from textile effluent. Furthermore, desorption studies showed about 95% of banana peel can be recovered with simple acid-base treatment.
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香蕉皮对纺织废水中染料的吸附特性研究
在地表水中处置活性染料污染物对受污染水源附近的水生生物和种群造成严重的健康风险。研究了香蕉皮在纺织工业活性染料中修复水污染的适用性。采用标准染料溶液进行了一组间歇实验,确定了最佳吸附参数,并将这些参数用于实际废水中染料的去除。将实验数据拟合到等温线和动力学模型中,表明单层染料吸附存在化学限制吸附步骤。模拟结果显示最大吸附量为28.8 mg/g。傅里叶变换红外(FTIR)光谱显示了羟基,胺和羧基的存在,有助于染料分子在吸附剂表面的高吸附。在最佳条件下(pH-7.0,初始染料浓度- 100 mg/L,接触时间- 60 min,吸附剂剂量- 0.5 g),标准溶液中约93%的染料被去除,而工业纺织废水的去除率为84.2%。这种差异主要是由于溶液的组成不同造成的。但对实际废水的去除率仍然很高,表明香蕉皮对纺织废水中染料的去除率具有很高的潜力。此外,解吸研究表明,简单酸碱处理可回收约95%的香蕉皮。
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