{"title":"Observations on selectivity reversal during chiral auxiliary-directed asymmetric nucleophile additions to arene–manganese tricarbonyl complexes","authors":"A. Pearson, M. Milletti, P. Zhu","doi":"10.1039/C39950000853","DOIUrl":null,"url":null,"abstract":"A study of hydride nucleophile reactions with η6-(2R, 5R)-dimethylpyrrolidinylbenzene–manganese tricarbonyl hexafluorophosphate 1 reveals an unexpected reversal of selectivity during addition of hydride to the diastereotopic meta carbons, which is explained on the basis of changes in transition state location as the reactivity of the nucleophile is varied.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"1 1","pages":"853-854"},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950000853","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3
Abstract
A study of hydride nucleophile reactions with η6-(2R, 5R)-dimethylpyrrolidinylbenzene–manganese tricarbonyl hexafluorophosphate 1 reveals an unexpected reversal of selectivity during addition of hydride to the diastereotopic meta carbons, which is explained on the basis of changes in transition state location as the reactivity of the nucleophile is varied.
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