5-Hydroxy-6-Methyluracil as a Polyvinyl Chloride Stabilizer

R. Akhmetkhanov, I. Gabitov, A. G. Mustafin, V. Zakharov, G. Zaikov
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Abstract

Kinetic regularities of thermooxidative dehydrochlorination of rigid and plasticized PVC in the presence of 5-hydroxy-6-methyluracil have been studied. The high antioxidant efficacy of 5-hydroxy-6-methyluracil in the process of polymer degradation has been revealed. It is shown that the studied uracil significantly slows down the process of accumulation of hydroperoxides in oxidation of dioctyl phthalate the plasticizer of PVC, which is the cause of a significant slowdown in the rate of decomposition of the plasticized polymer.
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5-羟基-6-甲基尿嘧啶作为聚氯乙烯稳定剂的研究
研究了硬质和增塑型PVC在5-羟基-6-甲基尿嘧啶存在下热氧化脱氢氯化反应的动力学规律。5-羟基-6-甲基尿嘧啶在聚合物降解过程中具有较高的抗氧化作用。结果表明,所研究的尿嘧啶显著减缓了聚氯乙烯增塑剂邻苯二甲酸二辛酯氧化过程中氢过氧化物的积累过程,这是导致增塑剂分解速度显著减慢的原因。
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