{"title":"Syntheses and Crystal Structures of [Cu3{-(NSPh2)2N}2Cl2] and [Cu3{-(NSPh2)2N}2{(NSPh2)2N}2]Cl2","authors":"T. Fujii, Mihoko Kanno, M. Hirata","doi":"10.1155/2010/326568","DOIUrl":null,"url":null,"abstract":"We have prepared the trinuclear complexes [Cu3{𝜇-(NSPh2)2N}2Cl2] (3) and [Cu3{𝜇-(NSPh2)2N}2{(NSPh2)2N}2]Cl2 (4), from the reaction of CuCl2 with {N(Ph2SN)(Ph2SNH)} (1) and determined their structures by X-ray crystallographic analysis. In both complexes, two monoanions 𝟏− chelate the Cu(II) center in square-planar geometry, whereas the terminal Cu(II) center is four-coordinate and a distorted tetrahedron.","PeriodicalId":14074,"journal":{"name":"International Journal of Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2010-02-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Inorganic Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1155/2010/326568","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
We have prepared the trinuclear complexes [Cu3{𝜇-(NSPh2)2N}2Cl2] (3) and [Cu3{𝜇-(NSPh2)2N}2{(NSPh2)2N}2]Cl2 (4), from the reaction of CuCl2 with {N(Ph2SN)(Ph2SNH)} (1) and determined their structures by X-ray crystallographic analysis. In both complexes, two monoanions 𝟏− chelate the Cu(II) center in square-planar geometry, whereas the terminal Cu(II) center is four-coordinate and a distorted tetrahedron.
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