CHAPTER 20. Cavity Effects in Metal–Organic Frameworks

Víctor L. Rechac, Encarnación Peris Sanchis, F. X. L. I. Xamena
{"title":"CHAPTER 20. Cavity Effects in Metal–Organic Frameworks","authors":"Víctor L. Rechac, Encarnación Peris Sanchis, F. X. L. I. Xamena","doi":"10.1039/9781788016490-00440","DOIUrl":null,"url":null,"abstract":"Metal–organic frameworks (MOFs) have attracted enormous interest in recent years owing to their potential use as heterogeneous catalysts. MOF catalysts can be designed with active sites at the metallic units or at the organic ligands or trapped inside their regular pore system. This chapter illustrates how cavity effects (i.e. the chemical environment in which the active sites are located) can have a large influence on their final catalytic properties through specific host–guest interactions, thereby introducing additional tools to modulate chemical specificity.","PeriodicalId":10054,"journal":{"name":"Catalysis Series","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2019-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Series","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/9781788016490-00440","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1

Abstract

Metal–organic frameworks (MOFs) have attracted enormous interest in recent years owing to their potential use as heterogeneous catalysts. MOF catalysts can be designed with active sites at the metallic units or at the organic ligands or trapped inside their regular pore system. This chapter illustrates how cavity effects (i.e. the chemical environment in which the active sites are located) can have a large influence on their final catalytic properties through specific host–guest interactions, thereby introducing additional tools to modulate chemical specificity.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
第20章。金属-有机骨架中的空腔效应
近年来,金属有机骨架(MOFs)因其作为多相催化剂的潜在用途而引起了人们的极大兴趣。MOF催化剂的活性位点可以设计在金属单元或有机配体上,或被困在其规则的孔隙系统中。本章阐述了空腔效应(即活性位点所在的化学环境)如何通过特定的主客体相互作用对其最终催化性能产生重大影响,从而引入了调节化学特异性的额外工具。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
Organocatalytic Dynamic Kinetic Resolution Chapter 2. Amavadin and Related Complexes as Oxidation Catalysts Catalysis with Earth-abundant Elements CHAPTER 5. Anion–π Catalysis CHAPTER 6. Onium Ion-assisted Organic Reactions Through Cation–π Interactions
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1