The removal of gallium from the lattice of MF1-gallosilicates as studied by 71Ga M.A.S-N.M.R spectroscopy

C. Bayense, Jan H C van Hooff, A. Kentgens, J. de Haan, L. van de Ven
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引用次数: 26

Abstract

Solid state 71Ga m.a.s.-n.m.r. spectroscopy on MFI-gallosilicates has shown evidence for the removal of tetrahedrally co-ordinated gallium from the zeolite lattice and the concomitant deposition of octahedrally co-ordinated gallium in the pores during steam treatment.
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用71Ga M.A.S-N.M研究了mf1 -低聚硅酸盐晶格中镓的去除。R光谱学
mfi -半硅酸盐的固态71Ga m.a.s.n m.mr光谱显示了沸石晶格中四面体配位镓的去除以及蒸汽处理过程中孔隙中伴随的八面体配位镓沉积的证据。
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