“TSC study on interfacial phenomena in micaloaded poly vinyl chloride (PVC) films”

P. Pillai, A. Tripathi, A. Tripathi, T. C. Goel
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引用次数: 1

Abstract

Thermoelectrets of solution cast films of PVC and PVC containing mica were prepared. Thermal depolarization current of these electrets has been measured to study the effect of polymer filler interface on the behaviour of carrier transport mechanism. A single dipolar peak has been observed in PVC around 90 °C, while two peaks (around 95 °C and 60 °C) are found in mica containing PVC, The peak around 95 °C in mica loaded PVC has been attributed to inter-facial phenomena which is confirmed by dielectric measurements as well as by TSC of electrets formed under a.c. fields using disimilar electrodes and blocking contacts.
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微负载聚氯乙烯(PVC)薄膜界面现象的TSC研究
制备了聚氯乙烯和含云母的聚氯乙烯溶液铸膜的热电极体。测量了这些驻极体的热去极化电流,研究了聚合物填料界面对载流子输运机理的影响。在90°C左右的聚氯乙烯中观察到一个单偶极峰,而在含有聚氯乙烯的云母中发现了两个峰(约95°C和60°C)。在云母负载的聚氯乙烯中,约95°C的峰归因于界面现象,这是由介电测量以及在交流场下使用不同电极和阻塞接触形成的极体的TSC证实的。
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