“Green” Extractants in the Recovery Processes of Non-ferrous Metal Ions from Technological Solutions

Andrey A. Voshkin, Y. Zakhodyaeva, I. V. Zinov’eva
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引用次数: 4

Abstract

The extraction of non-ferrous metal ions (Co, Ni, Cu, Al) from chloride solutions with poly(propylene glycol) 425 was studied. The values of the distribution coefficients and the degree of metal ions extraction are determined in the system under study. The mechanism of metal extraction in the poly(propylene glycol) 425 – sodium chloride– water extraction system in the presence of KSCN is described. The possibility of selective extraction of Co (II), Ni (II), Cu (II) and Al (III) from chloride solutions with poly(propylene glycol) 425 in the presence of KSCN is shown. Keywords: aqueous two-phase system, metal extraction, liquid–liquid equilibria, e-waste, poly(propylene glycol), sodium chloride
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“绿色”萃取剂在有色金属离子回收工艺中的应用
研究了用聚丙二醇425从氯化物溶液中萃取Co、Ni、Cu、Al等有色金属离子。确定了所研究体系的分配系数和金属离子的萃取程度。介绍了聚丙二醇425 -氯化钠-水萃取体系在KSCN存在下的金属萃取机理。在KSCN存在下,用聚丙二醇425从氯化物溶液中选择性萃取Co (II)、Ni (II)、Cu (II)和Al (III)的可能性。关键词:水两相体系,金属萃取,液-液平衡,电子垃圾,聚丙二醇,氯化钠
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