Properties of phase-separated soda-silica glasses as a means of investigation of their structure

O. Mazurin, G. Roskova, V. P. Kluyev
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引用次数: 24

Abstract

The influence of various heat-treatment on the viscosity, transformation temperature and electric conductivity of some soda-silica glasses in the immiscibility region was investigated. Two distinct temperature regions were found for several glasses. In one of the regions, heat-treatment leads to the “droplet” structure, whereas in the other it leads to the “two-framework” structure. The boundary between these regions was attributed to the boundary line of the spinodal region. A noticeable decrease in the transformation temperature of low-viscosity phase was found for the glass with a discontinuous low-viscosity phase. The uniform tension in droplets was assumed to be the cause of this effect.
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相分离钠硅玻璃的性质及其结构的研究
研究了不同热处理方式对非混相区钠硅玻璃的粘度、转变温度和电导率的影响。在几种玻璃中发现了两个不同的温度区域。在其中一个区域,热处理导致“液滴”结构,而在另一个区域,热处理导致“双框架”结构。这些区域之间的边界归属于脊柱区域的边界线。对于具有不连续低粘度相的玻璃,其低粘度相的转变温度明显降低。液滴的均匀张力被认为是造成这种效果的原因。
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