{"title":"Comments on “Solubility measurement, thermodynamic modeling and solubility parameters of clarithromycin (Form ӀӀ) in aqueous ethanolic solution”","authors":"Ramya Motati, Trisha Kandi, W. E. Acree","doi":"10.1080/00319104.2023.2218525","DOIUrl":null,"url":null,"abstract":"ABSTRACT Published numerical values of the curve-fit equation coefficients of the van’t Hoff model do not describe the observed mole fraction solubility data. Differences between the observed and back-calculated mole fraction solubilities differed by as much as one order of magnitude. Reanalysis of the published solubility data yielded completely different sets of equation coefficients.","PeriodicalId":20094,"journal":{"name":"Physics and Chemistry of Liquids","volume":null,"pages":null},"PeriodicalIF":1.2000,"publicationDate":"2023-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physics and Chemistry of Liquids","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1080/00319104.2023.2218525","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
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Abstract
ABSTRACT Published numerical values of the curve-fit equation coefficients of the van’t Hoff model do not describe the observed mole fraction solubility data. Differences between the observed and back-calculated mole fraction solubilities differed by as much as one order of magnitude. Reanalysis of the published solubility data yielded completely different sets of equation coefficients.
期刊介绍：
Physics and Chemistry of Liquids publishes experimental and theoretical papers, letters and reviews aimed at furthering the understanding of the liquid state. The coverage embraces the whole spectrum of liquids, from simple monatomic liquids and their mixtures, through charged liquids (e.g. ionic melts, liquid metals and their alloys, ions in aqueous solution, and metal-electrolyte systems) to molecular liquids of all kinds. It also covers quantum fluids and superfluids, such as Fermi and non-Fermi liquids, superconductors, Bose-Einstein condensates, correlated electron or spin assemblies.
By publishing papers on physical aspects of the liquid state as well as those with a mainly chemical focus, Physics and Chemistry of Liquids provides a medium for the publication of interdisciplinary papers on liquids serving its broad international readership of physicists and chemists.
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