Influence of SiO2 Micro- Particles on Microstructure, Mechanical Properties and Wear Resistance of UHMWPE Based Composite under Dry Sliding Friction

Noppanuch Puangmalee, N. Sonjaitham, Setthawit Saengthip, Noppanan Mungnuae, Surachade Solklin, S. Wannasri
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引用次数: 1

Abstract

This research investigated the influence of silicon dioxide (SiO2) with particle size of 5 micron on microstructure, mechanical properties and wear resistance of UHMWPE polymeric composite materials under dry sliding friction that was tested by Block–on–ring technique according to ASTM G77. Bulk UHMWPE composite specimen was reinforced with SiO2 particles by weight fraction of 0.1, 0.2, 0.3, 0.4, 0.5, 1, 2, 3, 4 and 5 wt.%. Specimen was performed by hot compression process with the compression forming conditions at the temperature of 202°C, pressure of 9.7 MPa and exposure time of 77 minutes. It was found that, SiO2 particle fraction in the range of not exceed than 0.5 wt.% did not affect to change microstructure of the specimen, which its microstructure did not significantly different from the initial UHMWPE specimen due to SiO2 particles were dispersed uniformly in the UHMWPE matrix. Its microstructure appeared in a spherulitic structure pattern. However, the increasing of SiO2 more than 0.5 wt.% affect to changed microstructure due to the SiO2 particles separated from the matrix and accumulated on the UHMWPE matrix. For the case of mechanical and wear resistance properties, the increasing of SiO2 particle of 0.5-1 wt.% affect to increased various mechanical properties to have a highest value and lowest wear rate as compared with initial UHMWPE up to 1.7 times. After that, the increasing of SiO2 particle affect to mechanical properties and wear resistance were decreased, except for the hardness that continuously increased according to the increasing of SiO2.
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SiO2微颗粒对UHMWPE基复合材料干滑动摩擦组织、力学性能和耐磨性的影响
本研究考察了粒径为5微米的二氧化硅(SiO2)对UHMWPE聚合物复合材料干滑动摩擦的微观结构、力学性能和耐磨性的影响,并根据ASTM G77采用块环技术进行了测试。用质量分数分别为0.1、0.2、0.3、0.4、0.5、1、2、3、4和5 wt %的SiO2颗粒增强块状UHMWPE复合材料试样。试样采用热压缩工艺,压缩成形条件为温度202℃,压力9.7 MPa,暴露时间77 min。结果表明,SiO2颗粒含量在不超过0.5 wt.%范围内对试样的微观结构没有影响,由于SiO2颗粒均匀地分散在UHMWPE基体中,其微观结构与初始UHMWPE试样的微观结构没有显著差异。其显微组织呈球晶结构。然而,当SiO2含量增加超过0.5 wt.%时,由于SiO2颗粒从基体中分离并积聚在超高分子量聚乙烯基体上,影响了微观结构的变化。在力学性能和耐磨性方面,SiO2颗粒含量增加0.5-1 wt.%对各种力学性能的提高有影响,与初始UHMWPE相比,其最高磨损率和最低磨损率达到1.7倍。之后,随着SiO2含量的增加,除硬度随SiO2含量的增加而不断增加外,对材料的力学性能和耐磨性的影响均有所降低。
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