Investigating the effect of gas flow rate and amount of zinc oxide nanoparticles on the efficacy of photocatalytic oxidation process of nitrogen oxide from waste airstream

Haji Omid Kalte, A. Jonidi, H. Asilian, A. Soleymanian
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Abstract

Nitrogen oxides are one of the most important air pollutants in environment and industrythat due to the adverse health and environmental effects should be refined before discharging into the environment. The photocatalytic oxidation method of nitrogen oxide into nitrogen Dioxide for better absorption insolutions is a promising method for removing of nitrogen oxides. Laboratory system used in this study is included of a source of gas source, mixing chamber, photocatalytic oxidation reactor, measuring system for nitrogen oxidation. Zinc oxide nanoparticles which were simulated by UV-A radiation would be used for photocatalytic oxidation.  Inlet concentration of nitrogen oxide and the amount of stabilized nanoparticles in reactor for converting nitrogen oxide into nitrogen dioxide has been investigated. Results showed that the amount of monotonic converting of nitrogen oxide into nitrogen dioxide in the amount of Nano-particles is stabilized 8mg/cm 2 for inlet concentration 100,150,200 ppm and respectively equivalent to 15, 26 and 32%. This study showed that increasing concentration of inletnitrogen oxide in system, reduce the capacity of photocatalytic oxidation for converting nitrogen oxide into nitrogen dioxide.
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研究了气流量和氧化锌纳米颗粒用量对废气流中氮氧化物光催化氧化效果的影响
氮氧化物是环境和工业中最重要的空气污染物之一,由于对人体健康和环境有不良影响,应在排放到环境中之前进行精炼处理。光催化氧化法将氮氧化物转化为二氧化氮以获得更好的吸附性,是一种很有前途的脱除氮氧化物的方法。本研究使用的实验室系统包括气源、混合室、光催化氧化反应器、氮氧化测量系统。紫外- a辐射模拟的氧化锌纳米颗粒将用于光催化氧化。研究了反应器中氮氧化物的进口浓度和稳定纳米颗粒的用量。结果表明,在进口浓度为100,150,200 ppm时,纳米颗粒量中氮氧化物单调转化为二氧化氮的量稳定在8mg/ cm2,分别相当于15%,26%和32%。本研究表明,增加系统进口氮氧化物浓度,会降低光催化氧化将氮氧化物转化为二氧化氮的能力。
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