Kinetic and Activation Characteristics of Structure Rearrangement Processes in Ethoxylated Isononylphenol Derivates

Abstract

The paper presents the calculation results of the kinetic and activation characteristics of fast and ultrafast structure rearrangement processes in liquid hydroxyethylated derivates of isononylphenol (ОНФn). Parameters were calculated using the relaxation theory of acoustic spectroscopy of liquids based on the analysis of the acoustic spectra of speed and sound absorption of the hydroxyethylated derivates of isononylphenol. The paper shows that two simple regions of acoustic dispersion can describe the acoustic spectra in the frequency range from 12 MHz to 2 GHz and the temperature range from 253 K to 323 K. The dispersion region data in the hydroxyethylated derivates of isononylphenol correspond to the interconnected reactions of OH ... O bonding and breaking in chain associates and spatially branched network structures. It is noted that the change in the spatial structure of liquid hydroxyethylated derivates of isononylphenol can be considered as a set of the large number of independent (for non-collective processes) and interconnected (for collective processes) local rearrangements of the liquid structure as a result of the thermal motion of molecules. The proposed molecular mechanism of acoustic relaxation and the kinetic model of fast and ultrafast structure rearrangement processes of the hydroxyethylated derivates of isononylphenol made it possible to explain the main experimental results and to calculate the kinetic and activation characteristics of the structure rearrangement processes of the hydroxyethylated derivates of isononylphenol. This model and the kinetic and activation parameters of the hydroxyethylated derivates of isononylphenol can find application in development of various technologies for using nonionic surfactants.