Low-temperature aging of composites on the basis system Al2O3 – [ZrYb]O2 including strontium hexaaluminate

L. I. Podzorova, A. Il’icheva, O. I. Pen’kova, V. Sirotinkin, O. Antonova, A. Baikin, G. Kochanov
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Abstract

The paper considers the effect of hydrothermal treatment, simulating a long stay in a biological environment, on the phase composition and bending strength of Al2O3 – [ZrYb]O2 composites containing a variable amount of Al2O3 and including strontium hexaaluminate. It has been shown that composites retain bending strength after hydrothermal action. This fact indicates the preservation of the phase composition in the volume of materials. It is determined that a monoclinic phase of zirconia is formed in the near-surface layer of the samples, the amount of which ranges from 11 to 9 %, correlating with the increase in the content of alumina in the composite. The formation of the monoclinic phase of zirconia in such an amount is well below the limit of 25 % specified in ISO 13356 2015 Implants for surgery — Ceramic materials based on yttria-stabilized tetragonal zirconia (Y-TZP). The results obtained make it possible to recommend Al2O3 – [ZrYb]O2 composites containing strontium hexaaluminate for medical applications.
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含六铝酸锶Al2O3 - [ZrYb]O2基体系复合材料的低温时效研究
本文研究了模拟在生物环境中长期停留的水热处理对含有可变Al2O3量和含六铝酸锶的Al2O3 - [ZrYb]O2复合材料相组成和抗弯强度的影响。研究表明,复合材料在热液作用下仍能保持抗弯强度。这一事实表明,相组成在材料体积中得到了保存。测定样品近表层形成单斜相氧化锆,其含量在11% ~ 9%之间,与复合材料中氧化铝含量的增加有关。这种数量的氧化锆单斜相的形成远远低于ISO 13356 2015外科植入物-基于钇稳定四边形氧化锆(Y-TZP)的陶瓷材料中规定的25%的限制。所得结果使推荐含有六铝酸锶的Al2O3 - [ZrYb]O2复合材料用于医疗应用成为可能。
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