Synthesis and Attestation of Titanium Dioxide Nanotubes Based Photocatalyst for Water and Air Purification out of Harmful Organic Impurities

A. Valeeva, I. B. Dorosheva, I. Weinstein, A. Rempel, E. Kozlova
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引用次数: 2

Abstract

In the present work we have synthesized nanotubular TiO2 film with a nonstoichiometric layer in the vicinity of titanium foil by anodization during 120 min. The catalytic activity of nanotubular titanium dioxide films formed during the oxidation of acetone to carbon dioxide under the action of visible light with a wavelength of 450 nm was found to be approximately 2 times higher compared to standard titanium dioxide (Degussa P25). Such a pronounced enhancement of activity may be attributed to a more efficient absorption of visible light by the films due to narrowing of the optical gap because of difference in the nonstoichiometry of titanium dioxide near the interface between nanotubular film and the titanium foil substrate. Keywords: photocatalysis, nonstoichiometric titanium dioxide, purification of water
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二氧化钛纳米管光催化剂的合成及对水和空气中有害有机杂质的净化
在本研究中,我们在120分钟的阳极氧化时间内,在钛箔附近合成了一层非化学计量层的纳米管二氧化钛薄膜。在波长为450 nm的可见光作用下,丙酮氧化成二氧化碳形成的纳米管二氧化钛薄膜的催化活性比标准二氧化钛(Degussa P25)高约2倍。这种明显的活性增强可能归因于薄膜对可见光的更有效吸收,这是由于纳米管薄膜和钛合金衬底之间界面附近二氧化钛的非化学计量差异导致光学间隙缩小。关键词:光催化,非化学计量二氧化钛,水净化
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