Intramolecular Cyclopropanation of Unsaturated Terminal Epoxides

IF 14.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Journal of the American Chemical Society Pub Date : 2004-06-24 DOI:10.1021/ja047346k
David M. Hodgson, Ying Kit Chung, Jean-Marc Paris
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引用次数: 52

Abstract

Efficient lithium amide-induced intramolecular cyclopropanation of bishomoallylic and trishomoallylic epoxides is described. The methodology is used in an asymmetric synthesis of sabina ketone.

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不饱和末端环氧化物的分子内环丙烷化反应
描述了锂酰胺诱导的双聚和三聚环氧化合物的分子内环丙烷化反应。该方法用于不对称合成萨比娜酮。
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来源期刊
CiteScore
24.40
自引率
6.00%
发文量
2398
审稿时长
1.6 months
期刊介绍: The flagship journal of the American Chemical Society, known as the Journal of the American Chemical Society (JACS), has been a prestigious publication since its establishment in 1879. It holds a preeminent position in the field of chemistry and related interdisciplinary sciences. JACS is committed to disseminating cutting-edge research papers, covering a wide range of topics, and encompasses approximately 19,000 pages of Articles, Communications, and Perspectives annually. With a weekly publication frequency, JACS plays a vital role in advancing the field of chemistry by providing essential research.
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