DEVELOPMENT OF MULTIFUNCTIONAL YARN FROM THE FUNCTIONALIZATION OF ORGANIC RAW COTTON FIBERS WITH ZINC NANOPARTICLES

S. Ferreira, P. Silva, J. Bessa, F. Cunha, C. Castro, A. Aguilar, R. Fangueiro
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Abstract

The emergence of increasingly contagious diseases in these days, such as COVID-19, increased the need to develop more effective personal protection equipment’s (PPEs). Therefore, the goal is to create textile materials capable to act against bacteria, virus or fungi, with a long-lasting performance but, at the same time, that could be comfortable and safe for their users. In this sense, based on the advantages of nanotechnology, the aim of this work was to functionalize organic raw cotton fibers with zinc nanoparticles (NPs) and previously tretated with NaOH, for the further production of multifunctional yarns with antimicrobial activity. Thereby, the fibers functionalization was tested using 1% w/w and 2% w/w of zinc NPs aqueous dispersion, being subsequently evaluated their distribution, chemical nature and zinc concentration by SEM/EDS and Atomic Absorption Spectroscopy, respectively. Subsequently, using the functionalized fibers, a yarn was spinned and their structural, mechanical and moisture management properties determined. Also, to assess the influence of the produced yarn on the properties of a fibrous structure, a single jersey knit sample was further produced and evaluated regarding their mechanical, moisture management and antibacterial properties. Based on the methodology used it was possible to develop a yarn with a tenacity 24% higher and a knit sample 28% more breathable and with a water evaporating ratio 37% higher than the one without any treatment or functionalization, but mainly with a strong antibacterial activity against both gram-negative (Klebsiella Pneumoniae) and gram-positive (Staphylococcus Aureus) bacteria, presenting therefore potential to be used in the production of effective PPEs.
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锌纳米粒子功能化有机原棉纤维开发多功能纱线
如今,COVID-19等传染性越来越强的疾病的出现,增加了开发更有效的个人防护装备(ppe)的需求。因此,我们的目标是创造出一种能够抵抗细菌、病毒或真菌的纺织材料,这种材料具有持久的性能,同时又能让用户感到舒适和安全。因此,基于纳米技术的优势,本研究的目的是利用纳米锌纳米粒子(NPs)对有机原棉纤维进行功能化,并对其进行氢氧化钠处理,以进一步生产具有抗菌活性的多功能纱线。因此,使用1% w/w和2% w/w的锌NPs水分散液来测试纤维的功能化,随后分别通过SEM/EDS和原子吸收光谱来评估它们的分布、化学性质和锌浓度。随后,利用功能化纤维纺成纱线,并测定其结构、机械和水分管理性能。此外,为了评估所生产的纱线对纤维结构性能的影响,进一步生产了一件针织衫样品,并评估了其机械、水分管理和抗菌性能。基于所使用的方法,与未经任何处理或功能化的纱线相比,可以开发出强度提高24%,针织样品透气性提高28%,水分蒸发率提高37%的纱线,但主要是对革兰氏阴性(肺炎克雷伯菌)和革兰氏阳性(金黄色葡萄球菌)细菌具有很强的抗菌活性,因此有可能用于生产有效的ppe。
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