Device engineering of organic solar cells based on a boron subphthalocyanine electron donor molecule

IF 2.9 4区 物理与天体物理 Q2 OPTICS Journal of Nonlinear Optical Physics & Materials Pub Date : 2022-12-21 DOI:10.1088/2515-7639/acada2
Mehrad Ahmadpour, M. Prete, Um Kanta Aryal, A. U. Petersen, Mariam Ahmad, H.-G. Rubahn, Malte F. Jespersen, K. Mikkelsen, V. Turkovic, M. Nielsen, M. Madsen
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Abstract

A boron subphthalocyanine molecule has been employed as a novel electron donor in organic solar cells (OPVs), and optimized in terms of composition and device structure in small molecule solar cells. It is demonstrated that the power conversion efficiency (PCE) of the devices obtained by solution-processing in bulk heterojunction solar cells could be improved by one order of magnitude by changing the fabrication method to vacuum deposition, which promotes a better morphology in the OPV active layers. Importantly, upon insertion of an additional pristine C70 thin interlayer between the active layer and the hole transport layer the PCE was further improved, highlighting the importance of interfacial layer engineering in such subphthalocyanine small molecule OPVs.
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基于亚酞菁硼电子给体分子的有机太阳能电池器件工程
将一种亚酞菁硼分子作为新型电子给体应用于有机太阳能电池中,并对其组成和器件结构进行了优化。结果表明,将制备方法改为真空沉积,可将采用溶液法制备的异质结太阳能电池器件的功率转换效率提高一个数量级,从而改善了OPV有源层的形貌。重要的是,在活性层和空孔传输层之间插入额外的原始C70薄夹层后,PCE得到了进一步改善,突出了界面层工程在这种亚酞菁小分子opv中的重要性。
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来源期刊
CiteScore
3.00
自引率
48.10%
发文量
53
审稿时长
3 months
期刊介绍: This journal is devoted to the rapidly advancing research and development in the field of nonlinear interactions of light with matter. Topics of interest include, but are not limited to, nonlinear optical materials, metamaterials and plasmonics, nano-photonic structures, stimulated scatterings, harmonic generations, wave mixing, real time holography, guided waves and solitons, bistabilities, instabilities and nonlinear dynamics, and their applications in laser and coherent lightwave amplification, guiding, switching, modulation, communication and information processing. Original papers, comprehensive reviews and rapid communications reporting original theories and observations are sought for in these and related areas. This journal will also publish proceedings of important international meetings and workshops. It is intended for graduate students, scientists and researchers in academic, industrial and government research institutions.
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