Zn(II) and Pd(II) Complexes of Thiosemicarbazone‐S‐alkyl Esters Derived from 2/3‐Formylpyridine

I. Kizilcikli,, B. Ülküseven, Y. Daşdemir, B. Akkurt
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引用次数: 31

Abstract

Abstract Representative S‐methyl/ethyl‐4‐H/phenylthiosemicarbazones and their Zn(II) and Pd(II) complexes were synthesized. Characterization of the 1:1 complexes, [Zn(L)Cl2], [Pd(L)Cl2], and [Pd(L)Cl]Cl, was accomplished by means of elemental analyses, IR and 1H NMR spectra. The multidentate S‐alkyl thiosemicarbazones coordinate as mono‐, bi‐, or tridentate ligands depending on the types of the alkyl moiety and metal ion.
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2/3 -甲酰基吡啶衍生的硫代氨基脲- S -烷基酯的Zn(II)和Pd(II)配合物
合成了具有代表性的S‐甲基/乙基‐4‐H/苯基硫代氨基脲及其Zn(II)和Pd(II)配合物。通过元素分析、IR和1H NMR表征了[Zn(L)Cl2]、[Pd(L)Cl2]和[Pd(L)Cl]Cl的1:1配合物。根据烷基部分和金属离子的类型,多齿S -烷基硫代氨基脲可以配位为单、双或三齿配体。
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