THE STUDY OF USING NATURAL FILLERS ON THE BIODEGRADATION PROPERTIES OF VIRGIN/WASTE LOW DENSITY POLYETHYLENE AND VIRGIN/WASTE HIGH DENSITY POLYETHYLENE COMPOSITES.

I. A. Dina, C. E. Gimba, A. Hamza, P. Ekwumemgbo
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Abstract

A study was carried out to check the effect of natural filler on the degradation properties of virgin and waste LDPE and virgin and waste HDPE. Samples were collected and compounded with Maleic Anhydride as a compatibilizer between the polymer matrix and PLA, starch and charcoal. Using the two-roll mix and the compression moulding machine for compounding, samples were moulded and cut according to specifications for the test. Tests carried out were done according to ASTM for water absorption, soil burial and QUV. Results showed as the amount of natural filler increased, it improved water absorption up to 42 days for both virgin LDPE and HDPE, while it took 180 days for samples with more percentage of natural fillers to record mass loss due to degradation. The SEM result confirmed a lot of cracks and holes as a result of immiscibility from the poly blends and which aided with high water absorption and degradation. The QUV results also showed degradation of all samples after exposure time in the accelerated weathering test.  
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利用天然填料对原/废低密度聚乙烯和原/废高密度聚乙烯复合材料生物降解性能的研究。
研究了天然填料对原LDPE和废LDPE、原HDPE和废HDPE降解性能的影响。收集样品,用马来酸酐作为聚合物基体与PLA、淀粉和木炭之间的增容剂进行复配。采用双辊混炼和压缩成型机混炼,按试验要求对试样进行成型和切割。根据ASTM对吸水率、土壤埋藏和QUV进行了测试。结果表明,随着天然填料含量的增加,纯LDPE和HDPE的吸水率均提高了42天,而天然填料含量较高的样品则需要180天才能达到降解造成的质量损失。扫描电镜结果证实,由于聚共混物的不混溶,导致了大量的裂纹和孔洞,这有助于高吸水性和降解。QUV结果还显示,在加速风化试验中,所有样品在暴露时间后都出现了退化。
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