ChemInform Abstract: Palladium—Copper Catalyzed C(sp3)—C(sp2) Bond C—H Activation Cross-Coupling Reaction: Selective Arylation to Synthesize 9-Aryl-9H-xanthene and 9,9-Diaryl-xanthene Derivatives.

ChemInform Pub Date : 2016-12-06 DOI:10.1002/chin.201652292
Guodong Shen, Lingyu Zhao, Yichen Wang, Wenfang Xia, Mingsen Yang, Tongxin Zhang
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Abstract

The Pd/Cu-catalyzed reaction of xanthenes (I) with arenes (II) gives rise to 9-aryl-9H-xanthenes (III) or 9,9-diaryl-xanthenes (VI) depending on the reaction time and temperature.

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摘要钯铜催化C(sp3) -C (sp2)键C - h活化交叉偶联反应:选择性芳基化合成9-芳基- 9h -杂蒽和9,9-二芳基-杂蒽衍生物。
在Pd/ cu催化下,黄原烯(I)与芳烃(II)的反应取决于反应时间和温度,生成9-芳基- 9h -黄原烯(III)或9,9-二芳基黄原烯(VI)。
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