Diclofenac Photodegradation Under Visible Light With (La,Ba)(Fe,Ti)O3 Perovskites

Ana Sofia Rodrigues, L. Ciríaco, Maria José Pacheco, A. Lopes
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Abstract

Perovskites BaTiO3 and BaFeO3 were prepared by the ceramic and complex polymerization methods and the substituted perovskites La0.2Ba0.8TiO3, BaFe0.8Ti0.2O3, and BaFe0.6Ti0.4O3 were prepared by the ceramic method. All of them were used as photocatalytic material for the degradation of the pharmaceutical diclofenac under visible light. The best diclofenac degradation results were obtained with the substituted perovskite La0.2Ba0.8TiO3 (46%), prepared by the ceramic method, and with the nonsubstituted perovskite BaFeO3 (43%), prepared by the complex polymerization method. Keywords: visible light, perovskites, photocatalysis, (La,Ba)(Fe,Ti)O3, diclofenac
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(La,Ba)(Fe,Ti)O3钙钛矿对双氯芬酸的可见光降解研究
采用陶瓷和络合聚合法制备了钙钛矿BaTiO3和BaFeO3,并采用陶瓷法制备了取代钙钛矿La0.2Ba0.8TiO3、BaFe0.8Ti0.2O3和BaFe0.6Ti0.4O3。将它们作为光催化材料在可见光下降解药物双氯芬酸。陶瓷法制备的取代钙钛矿La0.2Ba0.8TiO3(46%)和络合聚合法制备的非取代钙钛矿BaFeO3(43%)对双氯芬酸的降解效果最好。关键词:可见光,钙钛矿,光催化,(La,Ba)(Fe,Ti)O3,双氯芬酸
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