Copolymerization of diphosphonbutadienes with methyl methacrylate and styrene

Polymer Science U.s.s.r. Pub Date : 1974-01-01 Epub Date: 2003-06-11 DOI:10.1016/0032-3950(74)90335-9
S.V. Shulyndin, V.Sh. Gurskaya, M.K. Il'yina, V.A. Byl'yev, E.F. Gubanov, B.Ye. Ivanov
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引用次数: 3

Abstract

The radical copolymerization of methyl methacrylate and styrene with diphosphonbutadienes has been studied. The basic rules for the copolymerization process have been established and the relative activities of the copolymers investigated have been determined, as well as the specific activity Q and the polarity factor e of the diphosphonbutadienes. The chain transfer constants for the polymerization of methyl methacrylate in the presence of monomers containing phosphorus have been found. Certain properties of the copolymers containing phosphorus have been studied.

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二膦丁二烯与甲基丙烯酸甲酯和苯乙烯的共聚
研究了甲基丙烯酸甲酯和苯乙烯与二磷丁二烯的自由基共聚反应。建立了共聚过程的基本规律,测定了所研究共聚物的相对活度,以及二磷丁二烯的比活度Q和极性因子e。发现了在含磷单体存在下甲基丙烯酸甲酯聚合的链转移常数。研究了含磷共聚物的某些性质。
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Editorial Board Theoretical and experimental study of the catalytic degradation of polyisobutylene when exposed to strong lewis acids Influence of external effects on the structure and molecular dynamics of oriented copolymers and blends on the basis of polypropylene and polyethylene The change in the properties of blends of polypropylene and high-density polyethylene during high-shear extrusion Structure and properties of high-density polyethylene modified with a highly disperse Fe and FeO mixture
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