Hydrothermal Synthesis and Structural Characterization of a Three-Dimensional Coordination Polymer on Ag(I)

Qi Chen, Huijie Lun, Yong-Hong Li, Shu Li, Bei-Bei Li, Xudong Zhang, Yamin Li
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引用次数: 4

Abstract

A new coordination polymer [Ag3(1,2,4-btc)]n (1) (1,2,4-H3btc = 1,2,4-benzenetricarboxylate) has been synthesized by hydrothermal method and characterized by X-ray single crystal diffraction, elemental analysis, IR spectrum, and TGA. Compound 1 exhibits a 3D network consisting of the 2D layer connected by the ligand 1,2,4-btc3−, which adopts a new coordination mode. Moreover, blue fluorescence at 480 nm emission was observed under 320 nm excitation.
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Ag(I)三维配位聚合物的水热合成及结构表征
采用水热法合成了一种新型配位聚合物[Ag3(1,2,4-btc)]n (1) (1,2,4- h3btc = 1,2,4-苯三羧酸盐),并用x射线单晶衍射、元素分析、红外光谱和热重分析对其进行了表征。化合物1呈现由配体1,2,4-btc3−连接的二维层组成的三维网络,采用新的配位模式。在320 nm的激发下,观察到480 nm的蓝色荧光。
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