MECHANICAL RECYCLING OF SHORT CARBON FIBERS AND GROUND CARBON FIBERS REINFORCED PA66

Rebeka Lorber, M. Huskić, B. Nardin
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Abstract

Fiber-reinforced polymer composites occupy a fair share of structural and lightweight applications, replacing traditional materials whenever possible. Along with many advantages they offer, such as excellent mechanical properties to weight ratio, low price, fast production, the possibility of tailoring the properties for specific applications, etc. On the other hand, at the end of their lifetime, they are usually disposed of in landfills. Carbon fiber polymer composites (CFRPs) are relatively expensive materials and should be considered for recycling and reuse. Therefore, the influence of multiple cycles of mechanical recycling through grinding and injection molding was studied. PA66, PA66 reinforced with CF, and ground CF were mechanically recycled five times. Mechanical and thermal properties were determined after the first injection, as well as after the 1st, 3rd and 5th cycle of mechanical recycling. The values of mechanical properties (modulus, strength, ...) generally deteriorate, while the thermal properties remain almost unchanged. Part of the change is due to polymer degradation and part is due to fiber shortening.
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机械回收短碳纤维和磨碎碳纤维增强pa66
纤维增强聚合物复合材料在结构和轻量化应用中占有相当大的份额,尽可能取代传统材料。它们具有许多优点,例如优异的机械性能与重量比,低廉的价格,快速的生产,为特定应用量身定制性能的可能性等。另一方面,在它们的使用寿命结束时,它们通常被处理在垃圾填埋场。碳纤维聚合物复合材料(CFRPs)是相对昂贵的材料,应考虑回收和再利用。因此,研究了通过磨削和注射成型进行多次机械回收的影响。PA66、CF增强PA66、CF地面PA66机械回收5次。在第一次注射后以及第1、3、5次机械循环后测定其机械性能和热性能。力学性能(模量、强度等)一般会变差,而热性能几乎保持不变。这种变化部分是由于聚合物降解,部分是由于纤维缩短。
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