{"title":"The First Synthesis of p-Cl- and p-F-Phenylverbenene","authors":"Claudia A Contreras-Celedón, L. Chacón-García","doi":"10.2174/1874095200801020100","DOIUrl":null,"url":null,"abstract":"The first synthesis of 4´-X-phenylverbenene (X = F and Cl) via reaction of myrtenal with 4� -X phenylmagne- sium bromide and Bi(NO3)3 is described. Verbenene is formed due to the electron-withdrawing effect of the 4� - electronegative group, either fluorine or a Cl-Bi complex.","PeriodicalId":23020,"journal":{"name":"The Open Organic Chemistry Journal","volume":"27 1","pages":"100-106"},"PeriodicalIF":0.0000,"publicationDate":"2008-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Open Organic Chemistry Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2174/1874095200801020100","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The first synthesis of 4´-X-phenylverbenene (X = F and Cl) via reaction of myrtenal with 4� -X phenylmagne- sium bromide and Bi(NO3)3 is described. Verbenene is formed due to the electron-withdrawing effect of the 4� - electronegative group, either fluorine or a Cl-Bi complex.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
