Surface Treatment of Micro-fibrillated Cellulose Using Calcium Silicate Hydrate

Hirokazu Ito, M. Okamoto, Rie Makise, A. Isa, E. Fujinaka, Y. Kojima, Shigehiko Suzuki, T. Endo, Yoshikuni Teramoto
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引用次数: 2

Abstract

In the present study, we modified micro-fibrillated cellulose (MFC) mechano-chemically by a surface treatment with calcium silicate hydrate, in order to develop an effective filler material for producing wood-plastic composites (WPC). The surface modification could be performed efficiently by the combination of a wet ball-milling process in the presence of silica powder and Ca(OH)2 and a subsequent hydrothermal treatment, giving rise to a formation of tobermorite crystals of calcium silicate hydrate. The surface-treated MFC products exhibited high heat resistance and no irreversible aggregation even after normal heat-drying at 60°C. By an addition of the modified MFC filler to polypropylene-based WPC, the composite materials demonstrated high mechanical strength and high elastic modulus.
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水合硅酸钙对微纤纤维素的表面处理
本研究采用水合硅酸钙对微纤纤维素(MFC)进行机械化学改性,以开发一种生产木塑复合材料(WPC)的有效填充材料。通过在二氧化硅粉和Ca(OH)2存在下的湿球磨工艺和随后的水热处理相结合,可以有效地进行表面改性,从而形成水化硅酸钙的托贝莫来石晶体。经表面处理的MFC产品具有较高的耐热性,即使在60℃正常热干燥后也没有不可逆聚集。在聚丙烯基木塑材料中加入改性MFC填料,复合材料具有较高的机械强度和弹性模量。
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